Extrinsic Stains: Extrinsic stains are those that affect the outer surface of your teeth. These stains are typically caused by foods and beverages such as coffee, tea, red wine, and smoking. They are usually easier to remove and often come off during routine dental cleanings. Whitening toothpastes, which are designed to target surface stains, can help prevent new stains from forming. "They remove stains from the tooth surface, making the teeth appear brighter," Kahng says.However, if these extrinsic stains are left untreated for too long, they can penetrate deeper into the tooth structure, turning into intrinsic stains.